Alexandrion Drallipo (and her excellent Pre-Raphaelite eye) has once again given me a wonderful sighting for the Unexpected Pre-Raphaelite Sightings list. Thanks for the screen cap!
This is from The Thomas Crown Affair (1999) with Pierce Brosnan and Renee Russo. Unfortunately, my mind has gone blank and I can’t identify the painting. It looks like a Burne-Jones to me, but if anyone knows I hope you will post a comment.
At a different point in the film, you can see The Mirror of Venus by Burne-Jones, visible below around the 2:13 mark